Each AOL product has a reporting button that links to the help page to report inappropriate content. The content will be reviewed by AOL's Conditions of Service team who will take the appropriate action. You can find AOL's Web Services Agreement here.
MSN. You can find an online feedback form on the Microsoft website to report concerns about a range of Microsoft products, including MSN Web Messenger and MSN.co.uk. When in Windows Live Messenger, clicking the 'Help' tab will bring up a range of options, including 'Report Abuse'.
Go to the Yahoo! report abuse page for options on reporting incidents such as abusive emails or IMs, phishing and spam. You can find Yahoo's Terms of Service here.